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INTERGRANULAR CORROSION AND PHOSPHOR SEGREGATION AT GRAIN BOUNDAR1FS OF NON-SENSITIZED SUPERPURE AUSTENITIC STAINLESS STEEL 00Cr25Ni22Mo2N

FANG Yaohua Nanjing Institute of Chemical Technology , Nanjing , ChinaXU Yuan ZHANG Wenqi University of Science and Technology Beijing , Beijing , China FANG Yaohua Associate Professor , Dept.of Applied Chemistry , Nanjing Institute of Chemical Technology , Nanjing 210009 , China

金属学报(英文版)

The corrosion behaviour and mechanism of superpure austenitic stainless steel 00Cr25Ni22Mo2N in urea processing environment was studied using metallography,SEM, TEM,SIMS and AES techniques.The results show that the gas extraction tube made of non-sensitized 00Cr25Ni22Mo2N steel suffered intergranular corrosion.Corrosive media penetrated not only into the tube wall through grain boundaries but also expanded from the boundary towards the interior of the grain.Neither depletion of Cr nor precipitates were found at the grain boundaries.However,P(and Si)was segregated at the grain boundaries to a great extent.Semiquantitative calculation indicates that the P content at the grain boundaries is about 25 wt-%,three orders of magnitude higher than the content within the grain.Sugges- tion is made that the potential difference between the grain and its boundary due to the segre- gation results in the observed intergranular corrosion.

关键词: superpure austenitic stainless steel , null , null

Titanium technology in the USA - an overview

D.Eylon , S.R.Seagle

材料科学技术(英)

The state of Ti research, development and industry is reviewed in this article. The fifty-year anniversary of Ti technology commercialization in the USA provides an opportunity for a historical perspective. Incorporation of "information-age" tools into alloy development, processing, and production invigorates the technology. Consolidation, diversification and globalization have been transforming the Ti industry in the recent years.

关键词:

Theoretical Model of Steel Continuous Casting Technology

C Gheorghies , I Crudu , C Teletin , C Spanu

钢铁研究学报(英文版)

A theoretical model adapted for studying steel continuous casting technology was proposed. The model based on system theory contained input/output, command, and control parameters. The process was divided into five stages, ie, tundish, mold, guiding system, guidingdrawing system, and guidingdrawingsoft reduction system. The model can be used to describe the physicochemical processes, thermal processes, chemical processes, and characteristics of the cast material according to the abovementioned stages. It can also be applied to other metallurgical technologies and even to other industries (chemistry, food, etc).

关键词: steel;casting technology;system theory;modeling

SURFACE COMPOSITE GEAR AND PIPE MADE BY SEPARATED EUTECTIC TECHNOLOGY

Z.Q. Cao , L. Y Piao , X.G. Zhang , Z. Li and J.Z. jin(Research Center of Foundry Engineering , Dalian University of Technology , Dalian 116024 , China)

金属学报(英文版)

It is found that the anomalous eutectics can be separated on macroscopic scale by flow caused by electromagnetic stirring, and the separated phase is the leading faceted phase with the solution entmpy over 23J/(mol.K). By using this technology, a new kind of composite pipe ond gear with good abrasive properties are made without adding any reinforced particles. Emphases are paid on the researehes about formation mechanism of seporated eutectic and abrasive property of the composite pipe or gear. The result shows that the entropy of solution controlling the eutectic microstructure is also valid and useful as a criterion of separated eutectic, and the kind and its chemical scope of the off-eutectic used to make composite can be calculated accoofing to this theory.

关键词: composite pipe or gear , null , null , null

Development and application of universal formability technology

Yanwu Xu

材料科学技术(英)

Using mathematical plasticity theories, universal formability (UF) technology has been developed and applied in the automotive stamping engineering and production. As a formability analysis tool, this technology is the major methodology for the development of stamping expert system (solution provider) for (a) product design and feasibility analysis, (b) material automatic selection using nomograms, (c) draw die design using pre-models, and (d) UF and robustness analysis of die performance in finite element analysis (FEA) environment.

关键词:

Fabrication and microstructure of C/SiC composites using a novel heaterless chemical vapor infiltration technique

Journal of the American Ceramic Society

Fabrication of C/SiC composites by using the heaterless chemical vapor infiltration (HCVI) technique, which is an improved technology based on the conventional chemical vapor infiltration, is reported for the first time in this paper. In the HCVI process, a gradient temperature field formed in the fiber preform overcomes the problems of slow diffusion and restricted permeability of gaseous reactant species to some extent, and the electro-deposition is necessary to accelerate the SiC deposition rates. The highest linear deposition rates of SiC matrix within inter-fiber pores are 0.33 mu m/h. Microstructures of the C/SiC composites are uniform, and the inter-fiber and inter-ply pores can be well infiltrated. The longitudinal and circumferential microcracks are found in the composites.

关键词: deposition;behavior

Technology of Iron Carbide Synthesis

M. Bahgat , null

材料科学技术(英)

Iron carbides are very promising metallurgical products and can be used for steelmaking process, where it plays as an alternative raw material with significant economic advantages. Also it has many other applications, e.g. catalysts, magnets, sensors. The present review investigates the different properties and uses of the iron carbides. The commercial production and the different varieties for the iron carbides synthesis (gaseous carburization, mechanochemical synthesis, laser pyrolysis, plasma pyrolysis, chemical vapor deposition and ion implantation) were reviewed. Also the effect of different factors on the carburization process like gas composition, raw material, temperature, reaction time, catalyst presence and sulfur addition was indicated.

关键词: Iron carbides , null , null , null

Residual Stresses in Coating Technology

G.Montay , A.Cherouat , A.Nussair , J.Lu

材料科学技术(英)

Residual stress in coatings is the result of individual particle stress. Their effects may be either beneficial or detrimental, depending upon the magnitude, sign and distribution of the stresses with respect to the external load. Tensile stress which exceeds the elastic limit causes cracking in surface coatings or at the interface between the substrate and the coat. Compressive stress, in general, has a beneficial effect on the fatigue life, crack propagation, coating adhesion and on the durability of the top coat during service. Compressive residual stresses can increase the number of cycles before crack initiation begins through a mean stress effect. Temperature gradients which occur during solidification and subsequent cooling are the principal mode of internal stresses generation. Some parameters influence the residual stress field of both the coating and the substrate. Substrate nature, spraying temperature, thickness of the coat layer, substrate preparation (grit blasting conditions), and velocity of the splats are in the relation with the quality of the coating. In this work, we will describe the role playing by the ceramics coating elaboration on the residual stress gradient in depth of the component. The incremental hole drilling technique has been developed to determine the residual stress gradient in depth of the coat and substrate which must be used with particularly conditions. This new technology has been employed on zirconia, alumina and tungsten carbide plasma sprayed coating.

关键词: Coating , null , null , null

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